Ismail Qemali – Prime Minister and Minister of Foreign Affairs (December 4, 1912 – June 1913)
Myfid Bej Libohova – Minister of Foreign Affairs (June 1913 – January 22, 1914)
Turhan Pashë Përmeti – Prime Minister and Minister of Foreign Affairs (March 14, 1914 – May 20, 1914)
Preng Bibë Doda – Minister of Foreign Affairs (May 28, 1914 – September 3, 1914)
Pavli Terka – Minister of Foreign Affairs (October 5, 1914 – January 27, 1916)
Myfid Bey Libohova – Minister of Foreign Affairs (December 25, 1918 – January 29, 1920)
Mehmet Bey Konica – Minister of Foreign Affairs (January 30, 1920– November 14, 1920)
Iljaz Bej Vrioni – Prime Minister and Minister of Foreign Affairs (November 19, 1920 – July 1, 1921)
Pandeli Evangjeli – Prime Minister and Minister of Foreign Affairs (July 11 – October 6, 1921)
Pandeli Evangjeli – Prime Minister and Minister of Foreign Affairs (October 16, 1921 – December 6, 1921)
Fan Noli – Minister of Foreign Affairs (December 7, 1921 – December 12, 1921)
Xhaferr Bej Vila – Minister of Foreign Affairs (December 12, 1921 – December 24, 1921)
Fan Noli – Minister of Foreign Affairs – did not take this position. The task was taken over by Xhaferr Ypi – Prime Minister (December 24, 1921 – December 2, 1922)
Pandeli Evangjeli – Minister of Foreign Affairs (December 2, 1922 – February 25, 1924)
Iljaz Bej Vrioni – Minister of Foreign Affairs (March 30, 1924 – May 27, 1924)
Iljaz Bej Vrioni – Minister of Foreign Affairs (May 30, 1924 -June 10, 1924)
Sulejman Pashë Delvina – Minister of Foreign Affairs (June 16, 1924 – December 23, 1924)
Iljaz Bej Vrioni – Minister of Foreign Affairs (December 24, 1924 – January 5, 1925)
Monsignor Gjergj Koleci – Minister of Foreign Affairs – did not take this position. The task was taken over by Myfid Bej Libohova (January 6 – January 31, 1925)
Myfid Bej Libohova – Minister of Finance and Minister of Foreign Affairs (March 1, 1925 – September 23, 1925)
Hysen Bej Vrioni – Minister of Foreign Affairs (September 28, 1925 – February 10, 1927)
Iljaz Bej Vrioni – Minister of Foreign Affairs (February 12, 1927 – October 21, 1927)
Iljaz Bej Vrioni – Minister of Foreign Affairs (October 24, 1927 – May 10, 1928)
Iljaz Bej Vrioni – Minister of Foreign Affairs (May 11, 1928 – September 1, 1928)
Iljaz Bej Vrioni – Minister of Foreign Affairs (September 5, 1928 –January 13, 1929)
Rauf Fico – Minister of Foreign Affairs (January 14, 1929 –March 5, 1930)
Rauf Fico – Minister of Foreign Affairs (March 6, 1930 –April 11, 1931)
Hysen Bej Vrioni – Minister of Foreign Affairs (April 20, 1931 –December 7, 1932)
Xhaferr Bej Vila – Minister of Foreign Affairs (January 11, 1933 –October 6, 1935)
Fuat Asllani – Minister of Foreign Affairs (October 21, 1935 –November 7, 1936)
Ekrem Bey Libohova – Minister of Foreign Affairs (November 9, 1936 –April 2, 1939)
Mihal Sherko – Charge d’Affaires for Foreign Affairs in Provisional Administrative Committee (April 9, 1939 – April 12, 1939)
Xhemil Dino – Minister of Foreign Affairs (April 12, 1939 – June 3, 1939)
From June 3, 1939, the activity of foreign relations was taken over by the Italian Ministry of Foreign Affairs.
Mehmet Bej Konica – Minister of Foreign Affairs – did not take this position. The task was taken over by Rexhep Bej Mitrovica, Prime Minister (November 5, 1943 – February 6, 1944)
Bahri Omari – Minister of Foreign Affairs (February 6, 1944 – July 17, 1944)
Eqrem Bej Vlora – Minister of Foreign Affairs (July 18 – August 28, 1944)
Ibrahim Biçakçiu – Prime Minister and Minister of Foreign Affairs (September 6, 1944 – October 25, 1944)
Omer Nishani – Minister of Foreign Affairs (October 22, 1944 – January 10, 1946)
Omer Nishani – Minister of Foreign Affairs (January 11, 1946 – March 18, 1946)
Enver Hoxha – Prime Minister and Minister of Foreign Affairs (March 22, 1946 – June 30, 1950)
Enver Hoxha – Prime Minister and Minister of Foreign Affairs (July 5, 1950 – July 23, 1953)
Behar Shtylla – Minister of Foreign Affairs (July 23, 1953 – July 19, 1954)
Behar Shtylla – Minister of Foreign Affairs (July 20, 1954 – June 21, 1958)
Behar Shtylla – Minister of Foreign Affairs (June 22, 1958 –June 17, 1970)
Nesti Nase – Minister of Foreign Affairs (June 17, 1970 – October 29, 1974)
Nesti Nase – Minister of Foreign Affairs (October 29, 1974 – December 26, 1978)
Nesti Nase – Minister of Foreign Affairs (December 27, 1978 – June 30, 1982)
Reiz Malile – Minister of Foreign Affairs (June 30, 1982 – November 22, 1982)
Reiz Malile – Minister of Foreign Affairs (November 23, 1982 – February 21, 1987)
Reiz Malile – Minister of Foreign Affairs (February 20, 1987 – February 21, 1991)
Muhamet Kapllani – Minister of Foreign Affairs (February 22, 1991 – May 9, 1991)
Muhamet Kapllani – Minister of Foreign Affairs (May 9, 1991 – December 6, 1991)
Ilir Boçka – Minister of Foreign Affairs (December 18, 1991 – April 11, 1992)
Alfred Serreqi – Minister of Foreign Affairs (April 11, 1992 – July 11, 1996)
Tritan Shehu – Minister of Foreign Affairs (July 11, 1996 –April 12, 1997)
Arian Starova – Minister of Foreign Affairs (April 12, 1997 –July 25, 1997)
Paskal Milo – Minister of Foreign Affairs (July 25, 1997 –September 11, 2001)
Arta Dade – Minister of Foreign Affairs (September 11, 2001 –July 30,2002)
Ilir Meta – Deputy Prime Minister and Minister of Foreign Affairs (July 30, 2002 –July 18, 2003)
Luan Hajdaraga – Deputy Minister in Charge of the Ministerial Office (July 18, 2003 – December 28, 2003)
Kastriot Islami – Minister of Foreign Affairs (December 29, 2003 – September 11, 2005)
Besnik Mustafaj – Minister of Foreign Affairs (September 11, 2005 – May 1, 2007)
Lulzim Basha – Minister of Foreign Affairs (May 1, 2007 – September 17, 2009)
Ilir Meta – Minister of Foreign Affairs (September 17, 2009 – September 17, 2010)
Edmond Haxhinasto – Minister of Foreign Affairs (September 17, 2010 – July 2, 2012)
Edmond Panariti – Minister of Foreign Affairs (July 3, 2012 – April 4, 2013)
Aldo Bumçi – Minister of Foreign Affairs (April 4, 2013 – September 15, 2013)
Ditmir Bushati – Minister of Foreign Affairs (September 15, 2013 – January 21, 2019)
Edi Rama – Prime Minister and Minister for Europe and Foreign Affairs (the task was delegated to Gent Cakaj, Deputy Minister) (January 21, 2019 – January 4, 2021)
Olta Xhaçka – Minister for Europe and Foreign Affairs (January 5, 2021 –September 11, 2023)
Igli Hasani – Minister for Europe and Foreign Affairs (12 September 2023 – onwards)
